Gas-Phase Ionic Reactions: Dynamics and Mechanism of Nucleophilic Displacements-Reference-Cited by-同舟云学术

Gas-Phase Ionic Reactions: Dynamics and Mechanism of Nucleophilic Displacements

Published:1998-03-20 Issue:5358 Volume:279 Page:1882-1886
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Chabinyc Michael L.¹,Craig Stephen L.¹,Regan Colleen K.¹,Brauman John I.¹

Affiliation:

1. M. L. Chabinyc, C. K. Regan, and J. I. Brauman are in the Department of Chemistry, Stanford University, Stanford, CA 94305–5080, USA. S. L. Craig is in the Central Research and Development Department, E. I. DuPont de Nemours and Company, Incorporated, Wilmington, DE 19880–0328, USA.

Abstract

Nucleophilic displacement reactions (the S N 2 reaction) of ions in the gas phase are a prototypical reaction system that allows a study of dynamics, mechanisms, and structure-energy relations. This article reviews aspects of the kinetics (especially the applicability of statistical reaction rate theory), the relation of structure and reactivity, and the effects of small numbers of solvent molecules on the reaction and compares the behavior of the ionic reaction in the gas phase with that in solution.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference78 articles.

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