Biomimetic oxidation of cyclic and linear alkanes: high alcohol selectivity promoted by a novel manganese porphyrin catalyst

Author:

da Silva Vinicius Santos12345,dos Santos Vieira Warleson Cândido12345,Meireles Alexandre Moreira12345,Ucoski Geani Maria678910,Nakagaki Shirley678910,Idemori Ynara Marina12345,DeFreitas-Silva Gilson12345

Affiliation:

1. Departamento de Química

2. Instituto de Ciências Exatas

3. Universidade Federal de Minas Gerais (UFMG)

4. 31.270-901

5. Belo Horizonte

6. Laboratório de Bioinorgânica e Catálise

7. Departamento de Química – Centro Politécnico

8. Universidade Federal do Paraná (UFPR)

9. 81.531-980

10. Curitiba

Abstract

A novel β-brominated Mn-porphyrin acts as a good catalyst for alkane (cyclohexane, adamantine and n-hexane) oxidation in biomimetic systems.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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