Reaction of a nitrosyl complex of Mn(<scp>ii</scp>)–porphyrinate with superoxide: NOD activity is favoured over SOD activity-Reference-Cited by-同舟云学术

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Reaction of a nitrosyl complex of Mn(ii)–porphyrinate with superoxide: NOD activity is favoured over SOD activity

Published:2023 Issue:23 Volume:52 Page:7917-7925
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mazumdar Rakesh¹^ORCID,Saha Shankhadeep¹,Samanta Bapan¹,Ghosh Riya¹,Maity Sayani¹,Mondal Biplab¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Guwahati, North Guwahati, Assam-781039, India

Abstract

A {Mn(NO)}6 complex, [Mn(TMPP2−)(NO)], upon reaction with 2 equivalents of O2− in THF affords [MnIII(OH)] complex via a putative MnIII–peroxynitrite intermediate. Detailed studies have shown the preference of NOD activity over SOD-like activity.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00570D

Reference72 articles.

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2. Nitric Oxide and Infection , ed. F. C. Fang , Kluwer Academic/Plenum Publishers , New York , 1999

3. Myoglobin Catalyzes Its Own Nitration

4. Introduction: Nitric Oxide Chemistry

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