The polymerization of carvacrol catalyzed by Mn-porphyrins: obtaining the desired product guided by the choice of solvent, oxidant, and catalyst-Reference-Cited by-同舟云学术

The polymerization of carvacrol catalyzed by Mn-porphyrins: obtaining the desired product guided by the choice of solvent, oxidant, and catalyst

Published:2022 Issue:44 Volume:46 Page:21136-21147
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Tessaro Patrícia Salvador¹,Meireles Alexandre Moreira¹^ORCID,Guimarães Adriano Silva¹,Schmitberger Bernardo¹,Lage Ana Luísa Almeida¹,Patrício Patrícia Santiago de Oliveira²,Martins Dayse Carvalho da Silva¹^ORCID,DeFreitas-Silva Gilson¹^ORCID

Affiliation:

1. Departamento de Química, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, Belo Horizonte, MG, 31.270-901, Brazil

2. Departamento de Química, Centro Federal de Educação Tecnológica de Minas Gerais, Belo Horizonte, MG, 30.421-169, Brazil

Abstract

Less polar solvents could modulate the catalytic activity of Mn(iii)-porphyrins in carvacrol's oxidation leading to polymer/oligomer formation instead of thymoquinone formation.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Financiadora de Estudos e Projetos

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ03171J

Reference76 articles.

1. Carvacrol and human health: A comprehensive review

2. A Simple and Efficient Synthesis of Thymoquinone and Methyl P-Benzoquinone

3. Liquid-Phase Oxidation of Carvacrol Using Zeolite-Encapsulated Metal Complexes

4. Review on Molecular and Therapeutic Potential of Thymoquinone in Cancer

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