Capturing Re(i) in an neutral N,N,N pincer Scaffold and resulting enhanced absorption of visible light
Author:
Affiliation:
1. Department of Chemistry and Biomolecular Sciences
2. Centre for Catalysis Research and Innovation
3. University of Ottawa
4. Ottawa
5. Canada
Abstract
A family of Re(i) pincer complexes [κ3-2,6-{ArNCMe}2(NC5H3)]Re(CO)2X (ArC6H5, Me2C6H3, iPr2C6H3; X = Cl, Br) and (κ3-terpy)Re(CO)2X (X = Cl, Br) is accessed via an unconventional thermal transformation of bidentate complexes by heating in the solid state to 200–240 °C under nitrogen.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00661B
Reference61 articles.
1. Rhenium(I) tricarbonyl complexes with multidentate nitrogen-donor derivatives
2. Experimental Studies of Light-Induced Charge Transfer and Charge Redistribution in (X2-Bipyridine)ReI(CO)3Cl Complexes
3. Photochemical and photophysical processes in fac-Re(CO)3−(4-phenylpyridine)3(CF3SO3). Steady state and flash photolysis study
4. Design of luminescent iridium(III) and rhenium(I) polypyridine complexes as in vitro and in vivo ion, molecular and biological probes
5. Photophysical investigations of rhenium(I)Cl(CO)3(phenanthroline) complexes
Cited by 16 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Induced fac–mer rearrangements in {M(CO)3}+ complexes (M = Re, 99(m)Tc) by a PNP ligand;Dalton Transactions;2024
2. Electrocatalytic reduction of CO2 to CO by a series of organometallic Re(i)-tpy complexes;Dalton Transactions;2023
3. Anticancer and Antibiotic Rhenium Tri- and Dicarbonyl Complexes: Current Research and Future Perspectives;Molecules;2022-01-15
4. Dissecting conjugation and electronic effects on the linear and non-linear optical properties of rhenium(i) carbonyl complexes;Physical Chemistry Chemical Physics;2022
5. An Anthyridine-Based Pentanitrogen Donor Switches from Mono- to Tetradentate with Pd(II) Ions;Organometallics;2021-12-08
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3