Electrocatalytic reduction of CO2 to CO by a series of organometallic Re(i)-tpy complexes

Author:

Saha Shriya1ORCID,Doughty Thomas2ORCID,Banerjee Dibyendu3,Patel Sunil K.1ORCID,Mallick Dibyendu3ORCID,Iyer E. Siva Subramaniam1ORCID,Roy Souvik2ORCID,Mitra Raja1ORCID

Affiliation:

1. School of Chemical and Materials Sciences, Indian Institute of Technology Goa, Farmagudi, Goa 403401, India

2. School of Chemistry, University of Lincoln, Green Lane, Lincoln, Lincolnshire, LN6 7DL, UK

3. Department of Chemistry, Presidency University, Kolkata 700073, India

Abstract

This work describes the synthesis, spectroscopy, time-dependent density-functional theory (TDDFT) studies and electrocatalytic activity towards the CO2 reduction of 4′-substituted terpyridine ligand-coordinated Re(i) complexes.

Funder

Royal Society

Science and Engineering Research Board

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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