Coordination and insertion of alkenes and alkynes in AuIII complexes: nature of the intermediates from a computational perspective
Author:
Affiliation:
1. Centre for Theoretical and Computational Chemistry (CTCC) Department of Chemistry
2. University of Oslo
3. N-0315 Oslo
4. Norway
5. Institut Charles Gerhardt
6. Department of Chemistry
Abstract
Computational studies show how the stability and reactivity of gold(iii) alkene and alkyne complexes depend on the ancillary ligands.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT05014F
Reference69 articles.
1. Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions
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3. New developments in gold-catalyzed manipulation of inactivated alkenes
4. Effective transformation of unactivated alkynes into ketones or acetals with a gold(III) catalyst
5. A New Gold-Catalyzed C−C Bond Formation
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