Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(<scp>i</scp>) compounds: squarate dianion <i>vs.</i> metallo-ketene formation-Reference-Cited by-同舟云学术

Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(i) compounds: squarate dianion vs. metallo-ketene formation

Published:2023 Issue:19 Volume:14 Page:5188-5195
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yuvaraj K.¹^ORCID,Mullins Jeremy C.¹,Rajeshkumar Thayalan²,Douair Iskander²^ORCID,Maron Laurent²^ORCID,Jones Cameron¹^ORCID

Affiliation:

1. School of Chemistry, Monash University, PO Box 23, VIC, 3800, Australia

2. Université de Toulouse et CNRS, INSA, UPS, LPCNO, UMR 5215, 135 Avenue de Rangueil, F-31077 Toulouse, France

Abstract

The reductive tetramerisation of CO by Lewis base activated dimagnesium(i) compounds, in the presence of Mo(CO)6, led to the competitive formation of magnesium squarate and metallo-ketene complexes (see picture).

Funder

Air Force Office of Scientific Research

Alexander von Humboldt-Stiftung

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01487H

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