Mechanistic investigations of the Fe(ii) mediated synthesis of squaraines

Author:

Liu Yu1ORCID,Coles Nathan T.1ORCID,Cajiao Nathalia23ORCID,Taylor Laurence J.1ORCID,Davies E. Stephen1,Barbour Alistair1,Morgan Patrick J.1,Butler Kevin1ORCID,Pointer-Gleadhill Ben1,Argent Stephen P.1ORCID,McMaster Jonathan1,Neidig Michael L.2ORCID,Robinson David4ORCID,Kays Deborah L.1ORCID

Affiliation:

1. School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK

2. Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK

3. Department of Chemistry, University of Rochester, Rochester, New York 14627, USA

4. Department of Chemistry and Forensics, School of Science and Technology, Nottingham Trent University, Nottingham, NG11 8NS, UK

Abstract

In situ monitoring and reaction sampling (IR, NMR, EPR, Mössbauer spectroscopy) and structural characterisation of isolable species allows detailed mechanistic insight into the scission/homologation of CO by two-coordinate iron terphenyl complexes.

Funder

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

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