Steric control of Mg–Mg bond formation <i>vs.</i> N<sub>2</sub> activation in the reduction of bulky magnesium diamide complexes-Reference-Cited by-同舟云学术

Steric control of Mg–Mg bond formation vs. N₂ activation in the reduction of bulky magnesium diamide complexes

Published:2024 Issue:8 Volume:60 Page:1016-1019
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mondal Rahul¹,Evans Matthew J.¹,Nguyen Dat T.¹,Rajeshkumar Thayalan²,Maron Laurent²^ORCID,Jones Cameron¹^ORCID

Affiliation:

1. School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800, Australia

2. Université de Toulouse et CNRS, INSA, UPS, UMR5215, LPCNO, 135 Avenue de Rangueil, Toulouse 31077, France

Abstract

Reduction of a bulky diamido-magnesium(ii) complex has yielded the potassium salt of a dimagnesium(i) dianion, whereas prior reduction of a bulkier analogue gave an activated N2 complex. The relevance of ligand bulk in these processes is discussed.

Funder

Air Force Office of Scientific Research

Alexander von Humboldt-Stiftung

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05787A

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5. Mg–Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

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