Construction of trifluoromethylated quaternary stereocenters via p-quinone methides-Reference-Cited by-同舟云学术

Construction of trifluoromethylated quaternary stereocenters via p-quinone methides

Published:2020 Issue:20 Volume:56 Page:3031-3034
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Terashima Kyu¹²³⁴⁵,Kawasaki-Takasuka Tomoko¹²³⁴⁵^ORCID,Agou Tomohiro⁶⁷⁸⁵^ORCID,Kubota Toshio⁶⁷⁸⁵^ORCID,Yamazaki Takashi¹²³⁴⁵^ORCID

Affiliation:

1. Division of Applied Chemistry

2. Institute of Engineering

3. Tokyo University of Agriculture and Technology

4. Koganei 184-8588

5. Japan

6. Department of Biomolecular Functional Engineering

7. Ibaraki University

8. Hitachi 316-8511

Abstract

Development of a new synthetic method for the construction of quaternary centers with a CF₃ group was realized by way of 1,6-addition of various nucleophiles to highly reactive δ-trifluoromethylated p-quinone methides generated in situ.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08936E

Reference41 articles.

1. Reactions of CF3-enones with arenes under superelectrophilic activation: a pathway to trans-1,3-diaryl-1-CF3-indanes, new cannabinoid receptor ligands

2. Construction of Optically Active CF3-Containing Quaternary Carbon Centers via Stereospecific SN2‘ Reaction

3. Formation of Quaternary Carbon Center with a Trifluoromethyl Group Using a Pd-Catalyzed Allylation Reaction

4. Organocatalytic Asymmetric Synthesis of Trifluoromethyl-substituted Diarylpyrrolines: Enantioselective Conjugate Cyanation of β-Aryl-β-trifluoromethyl-disubstituted Enones

5. Organocatalytic Enantioselective Synthesis of Dihydropyrano- indole Derivatives Bearing Trifluoromethylated All-Carbon- Substituted Stereocenters

Cited by 17 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Creation of a Chiral All-Carbon Quaternary Center Induced by CF₃ and CH₃ Substituents via Cu-Catalyzed Asymmetric Conjugate Addition;Organic Letters;2024-06-13

2. Phosphine-Catalyzed Domino Annulation of γ-Vinyl Allenoates: Synthesis of Tetrahydrofuro[3,2-c]quinoline Derivatives;Organic Letters;2024-05-08

3. Copper‐Catalyzed Benzylic Functionalization of Lignin‐Derived Monomers;ChemSusChem;2023-08-17

4. Copper (I) Chloride‐Catalyzed Photoredox Synthesis of Multifunctionalized Compounds at Room Temperature and Their Antifungal Activities;Chemistry – A European Journal;2023-03-09

5. Construction of CF<sub>3</sub>-containing Tetrasubstituted Carbon Frameworks by Way of <i>p</i>-Quinone Methides;Journal of Synthetic Organic Chemistry, Japan;2023-03-01