IF5 affects the final stage of the Cl–F exchange fluorination in the synthesis of pentafluoro-λ6-sulfanyl-pyridines, pyrimidines and benzenes with electron-withdrawing substituents-Reference-Cited by-同舟云学术

IF5 affects the final stage of the Cl–F exchange fluorination in the synthesis of pentafluoro-λ6-sulfanyl-pyridines, pyrimidines and benzenes with electron-withdrawing substituents

Published:2017 Issue:44 Volume:53 Page:5997-6000
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cui Benqiang¹²³⁴,Kosobokov Mikhail¹²³⁴,Matsuzaki Kohei¹²³⁴,Tokunaga Etsuko¹²³⁴,Shibata Norio¹²³⁴^ORCID

Affiliation:

1. Department of Nanopharmaceutical Sciences

2. Nagoya Institute of Technology

3. Nagoya 466-8555

4. Japan

Abstract

SF₅-(hetero)arenes having electron-deficient groups were efficiently synthesized by oxidative chlorotetrafluorination followed by a S_Ni-type Cl–F exchange reaction using IF₅.

Funder

Japan Science and Technology Agency

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC02802D

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