Fluoroalkylated hypervalent sulfur fluorides: radical addition of arylchlorotetrafluoro-λ<sup>6</sup>-sulfanes to tetrafluoroethylene-Reference-Cited by-同舟云学术

Fluoroalkylated hypervalent sulfur fluorides: radical addition of arylchlorotetrafluoro-λ⁶-sulfanes to tetrafluoroethylene

Published:2023 Issue:43 Volume:14 Page:12379-12385
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yasuo Eisuke¹,Aikawa Kohsuke¹^ORCID,Nozaki Kyoko²^ORCID,Okazoe Takashi¹³

Affiliation:

1. Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-0032, Japan

2. Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

3. Yokohama Technical Center, AGC Inc., 1-1 Suehiro-cho, Tsurumi-ku, Yokohama 230-0045, Japan

Abstract

Unprecedented aryl(polyfluoroethyl)tetrafluoro-λ6-sulfanes were synthesized via the radical addition of arylchlorotetrafluoro-λ6-sulfanes to tetrafluoroethylene. The bridging tetrafluoro-λ6-sulfanyl moiety strongly enhanced the hydrophobicity.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC04837C

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