Visible light-assisted organocatalytic α-acyloxylation of ketones using carboxylic acids and <i>N</i>-halosuccinimides-Reference-Cited by-同舟云学术

Visible light-assisted organocatalytic α-acyloxylation of ketones using carboxylic acids and N-halosuccinimides

Published:2022 Issue:80 Volume:58 Page:11308-11311
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sakkani Nagaraju¹,Jha Dhiraj K.¹,Whatley Emily¹,Zhao John C.-G.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX, 78249-0698, USA

Abstract

The α-acyloxylketone motif can be found in many important pharmaceuticals and biologically active natural products and their derivatives. Now we have realized a direct synthesis of α-acyloxylketones from ketones and readily available carboxylic acids using a photo-assisted organocatalytic reaction.

Funder

Welch Foundation

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04016F

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