Visible Light‐Assisted Direct C−H Acyloxylation of Polycyclic Aromatic Hydrocarbons using Carboxylic Acids-Reference-Cited by-同舟云学术

Visible Light‐Assisted Direct C−H Acyloxylation of Polycyclic Aromatic Hydrocarbons using Carboxylic Acids

Published:2023-05-12 Issue:10 Volume:365 Page:1585-1590
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

K. Jha Dhiraj¹,Sakkani Nagaraju¹²,Zhao John C.‐G.¹^ORCID

Affiliation:

1. Department of Chemistry University of Texas at San Antonio One UTSA Circle San Antonio TX 78249-0698 USA

2. Current address: Medicines for All Institute Virginia Commonwealth University 737 N 5th Street Richmond VA 23219 USA

Abstract

AbstractThe direct C−H acyloxylation of polycyclic aromatic hydrocarbons (PAHs) with carboxylic acids as the acyloxylating agents was achieved via the electron‐donor‐acceptor (EDA) complexes between PAHs and N‐iodosuccinimide (NIS). This visible light‐assisted metal‐free C−H acyloxylation reaction provides an easy access to the desired aryl carboxylates from readily available PAHs and aliphatic and aromatic carboxylic acids under mild reaction conditions.

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Funder

Welch Foundation

National Science Foundation

Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/adsc.202300043

Reference58 articles.

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4. Q. Miao Polycyclic Arenes Heteroarenes: Synthesis Properties and Applications Wiley-VCH Weinheim 2015.

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