KI-catalyzed α-acyloxylation of acetone with carboxylic acids-Reference-Cited by-同舟云学术

KI-catalyzed α-acyloxylation of acetone with carboxylic acids

Published:2016 Issue:25 Volume:14 Page:5936-5939
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wu Ya-Dong¹²³⁴,Huang Bei⁵³⁴,Zhang Yue-Xin⁵³⁴,Wang Xiao-Xu⁵³⁴,Dai Jian-Jun⁵³⁴,Xu Jun⁵³⁴,Xu Hua-Jian⁵³⁴

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Hefei University of Technology

3. Hefei 230009

4. P. R. China

5. School of Medical Engineering

Abstract

A KI catalyzed reaction of acetone with aromatic carboxylic acids is achieved, leading to α-acyloxycarbonyl compounds in good to excellent yields under mild reaction conditions. The present method exhibits good functional-group compatibility.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00876C

Reference45 articles.

1. N-Heterocyclic carbene catalyzed regioselective oxo-acyloxylation of alkenes with aromatic aldehydes: a high yield synthesis of α-acyloxy ketones and esters

2. Synthesis of Multisubstituted Furans, Pyrroles, and Thiophenes via Ynolates

3. Ruthenium-catalyzed oxidative transformation of alkenes to .alpha.-ketols with peracetic acid. Simple synthesis of cortisone acetate

4. A New Route to Protected Acyloins and Their Enzymatic Resolution with Lipases

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