Proximity enforced oxidative addition of a strong unpolar σ-Si–Si bond at rhodium(i)
Author:
Affiliation:
1. Institut für Anorganische Chemie und Kristallographie
2. Fachbereich 2-Biologie/Chemie
3. Universität Bremen
4. 28359 Bremen
5. Germany
6. Institut für Experimentalphysik
7. Freie Universität Berlin
8. 14195 Berlin
Abstract
After the oxidative addition, the two Si atoms are still engaged in weak, non-covalent, London dispersion type interactions.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00017E
Reference37 articles.
1. Activation of the Si-Si Bond by Transition Metal Complexes
2. Transition-Metal-Catalyzed Additions of Silicon−Silicon and Silicon−Heteroatom Bonds to Unsaturated Organic Molecules
3. Element−Element Additions to Unsaturated Carbon−Carbon Bonds Catalyzed by Transition Metal Complexes
4. Rh(I)-Catalyzed Silylation of Aryl and Alkenyl Cyanides Involving the Cleavage of C−C and Si−Si Bonds
5. Rhodium-Catalyzed Silylation and Intramolecular Arylation of Nitriles via the Silicon-Assisted Cleavage of Carbon−Cyano Bonds
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