Different Reactivities of (5-Ph2P-Ace-6-)2MeSiH toward the Rhodium(I) Chlorides [(C2H4)2RhCl]2 and [(CO)2RhCl]2. Hirshfeld Atom Refinement of a Rh–H···Si Interaction-Reference-Cited by-同舟云学术

Different Reactivities of (5-Ph2P-Ace-6-)2MeSiH toward the Rhodium(I) Chlorides [(C2H4)2RhCl]2 and [(CO)2RhCl]2. Hirshfeld Atom Refinement of a Rh–H···Si Interaction

Published:2021-06-21 Issue:13 Volume:40 Page:2027-2038
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Holsten Sebastian¹,Malaspina Lorraine A.²,Kleemiss Florian²^ORCID,Mebs Stefan³^ORCID,Hupf Emanuel¹,Grabowsky Simon²^ORCID,Beckmann Jens¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359 Bremen, Germany

2. Departement für Chemie, Biochemie und Pharmazie, Universität Bern, Freiestrasse 3, 3012 Bern, Switzerland

3. Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany

Funder

Deutsche Forschungsgemeinschaft

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.0c00804

Reference140 articles.

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4. Phosphinoalkylsilyl Complexes. 12. Stereochemistry of the Tridentate Bis(diphenylphosphinopropyl)silyl (biPSi) Framework: Complexation That Introduces “Face Discrimination” at Coordinatively Unsaturated Metal Centers. X-ray Crystal and Molecular Structures of Pt[SiMe(CH2CH2CH2PPh2)2]Cl, IrH[SiMe(CH2CH2CH2PPh2)2]Cl, and RuH[SiMe(CH2CH2CH2PPh2)2](CO)21

5. Iridium Compounds with κ-P,P,Si (biPSi) Pincer Ligands: Favoring Reactive Structures in Unsaturated Complexes

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