Phosphinoalkylsilyl Complexes. 12. Stereochemistry of the Tridentate Bis(diphenylphosphinopropyl)silyl (biPSi) Framework: Complexation That Introduces “Face Discrimination” at Coordinatively Unsaturated Metal Centers. X-ray Crystal and Molecular Structures of Pt[SiMe(CH2CH2CH2PPh2)2]Cl, IrH[SiMe(CH2CH2CH2PPh2)2]Cl, and RuH[SiMe(CH2CH2CH2PPh2)2](CO)21
Author:
Affiliation:
1. Department of Chemistry, Auburn University, Auburn, Alabama 36849
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om970518k
Reference51 articles.
1. (Phosphinoalkyl)silyl Complexes. 11.1 Structural Influence of the Chelate Dimethyl((diphenylphosphino)ethyl)silyl Group. Irregular 5-Coordinate Geometry at a d6 Center. X-ray Crystal and Molecular Structures of Three Silyliridium(III) Complexes [Ir(chel)2Cl, IrH(chel)(PPh3)(CO)Cl, IrH(chel)(cod)Cl; chel = PPh2CH2CH2SiMe2−, cod = Cycloocta-1,5-diene]
2. Enantiofacially Selective Binding of Prochiral Olefins to a Chiral Catalyst via Simultaneous Face−Face and Edge−Face Aromatic Interactions
3. Asymmetric Catalysis. Asymmetric Catalytic Intramolecular Hydroacylation of 4-Pentenals Using Chiral Rhodium Diphosphine Catalysts
4. Asymmetric Hydrogenation Reactions Using Chiral Diphosphine Complexes of Rhodium
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