Practical method for hydroxyl-group protection using strontium metal and readily available silyl chlorides-Reference-Cited by-同舟云学术

Practical method for hydroxyl-group protection using strontium metal and readily available silyl chlorides

Published:2022 Issue:43 Volume:58 Page:6312-6315
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Miyoshi Norikazu¹²^ORCID,Miyoshi Aki¹,Miyazaki Yasuaki²,Kubo Shigeki²,Ueno Masaharu¹²^ORCID

Affiliation:

1. Department of Natural Science, Graduate School of Advanced Technology and Science, Tokushima University, 2-1 Minami-jousanjima, Tokushima 770-8506, Japan

2. Department of Chemistry, Faculty of Integrated Arts and Sciences, Tokushima University, 1-1 Minami-jousanjima, Tokushima 770-8502, Japan

Abstract

We have found that the etherification of silyl-protected secondary alcohols proceeds smoothly in the presence of strontium metal using silyl chloride instead of the expensive, yet more reactive, and commonly used silyl triflate.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01105K

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