Cu-mediated vs. Cu-free selective borylation of aryl alkyl sulfones

Author:

Huang Mingming1,Tang Man2,Hu Jiefeng1,Westcott Stephen A.3,Radius Udo1ORCID,Marder Todd B.1ORCID

Affiliation:

1. Institute for Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany

2. School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

3. Department of Chemistry & Biochemistry, Mount Allison University, Sackville, NB E4L 1G8, Canada

Abstract

Borylation of cyclic aryl–alkyl sulfones gives boronate esters by selective cleavage of C(sp2)–SO2 or C(sp3)–SO2 bonds via Cu-mediated or Cu-free processes.

Funder

Alexander von Humboldt-Stiftung

Natural Science Foundation of Jiangsu Province

China Scholarship Council

Julius-Maximilians-Universität Würzburg

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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