Ligand-enabled silver-catalyzed carbene insertion into the N–H bond of aliphatic and electron-rich aromatic amines-Reference-Cited by-同舟云学术

Ligand-enabled silver-catalyzed carbene insertion into the N–H bond of aliphatic and electron-rich aromatic amines

Published:2023 Issue:7 Volume:10 Page:1746-1753
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Li Linxuan¹,Sivaguru Paramasivam¹,Han Xinyue¹,Karmakar Swastik²^ORCID,Bi Xihe¹³^ORCID

Affiliation:

1. Department of Chemistry, Northeast Normal University, Changchun 130024, China

2. Department of Chemistry, Basirhat College, West Bengal State University, Basirhat-743412, West Bengal, India

3. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Abstract

The stable effect of tris(pyrazolyl)borate ligand and 1,2-diaminocyclohexane ligand on the silver metal center was used respectively, to realize the efficient N–H bond insertion reaction of carbene to aliphatic amines and aromatic amines.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Department of Science and Technology of Jilin Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00156C

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