Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me3SiN3: a new synthetic route to complexes with beautiful structures and diverse magnetic properties
Author:
Affiliation:
1. Department of Chemistry
2. 1812 Sir Isaac Brock Way
3. Brock University
4. L2S 3A1 St. Catharines
5. Canada
6. Institute of Inorganic and Analytical Chemistry
7. Johannes Gutenberg University Mainz
8. D-55128 Mainz
9. Germany
Abstract
A new synthetic route to structurally novel and magnetically interesting 3d-metal azido clusters and coordination polymers is presented; the key reagent for the preparation of solely azido-bridged molecule-based species is the organic azide precursor Me3SiN3.
Funder
Brock University
Ministry of Research and Innovation
Natural Sciences and Engineering Research Council of Canada
Alexander von Humboldt-Stiftung
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC08854C
Reference132 articles.
1. Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions
2. R. Clérac and R. E. P.Winpenny , Single-Molecule Magnets and Related Phenomena , in 50 Years of Structure and Bonding – The Anniversary Volume , ed. D. Mingos , Springer , Structure and Bonding, 2016 , 172 , pp. 35–48
3. Intriguing aspects of lanthanide luminescence
4. Magnetic Molecular Conductors
5. Transformative 3d–4f coordination cluster carriers
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