Aminocarbyne coupling reactions at M(Ph2PCH2CH2PPh2)2(M = Mo or W) sites. Synthesis and properties of the diaminoacetylene complexes trans-[MX(η2-MeHNCCNHMe)-(Ph2PCH2CH2PPh2)2]A (X = F, Cl or ClO4; A = BF4′PF6′HCl2or ClO4) and of their di(aminocarbyne)-type precursors-Reference-Cited by-同舟云学术

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Aminocarbyne coupling reactions at M(Ph2PCH2CH2PPh2)2(M = Mo or W) sites. Synthesis and properties of the diaminoacetylene complexes trans-[MX(η2-MeHNCCNHMe)-(Ph2PCH2CH2PPh2)2]A (X = F, Cl or ClO4; A = BF4′PF6′HCl2or ClO4) and of their di(aminocarbyne)-type precursors

Published:1995 Issue:7 Volume: Page:1183-1191
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Wang Yu,Da Silva João J. R. Fraústo,Pombeiro Armando J. L.,Pellinghelli Maria Angela,Tiripicchio António,Henderson Richard A.,Richards Raymond L.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950001183

Reference46 articles.

1. Aminocarbyne coupling reactions leading to the bis(amino)acetylene complexes trans-[MF(η2-MeHNCCNHMe)-(Ph2PCH2CH2PPh2

2. The 15 years of reductive coupling: what have we learned?

3. Reductive Coupling of Carbon Monoxide and Alkyl Isocyanide Ligands in Early Transition Metal Complexes: A Review

4. Mechanistic studies of the reductive coupling of carbon monoxide in seven-coordinate niobium(I) and tantalum(I) dicarbonyl complexes

5. Mechanistic studies of the reductive coupling of isocyanides in seven-co-ordinate molybdenum complexes; X-ray crystal structures of [Mo(CNBut)6] and [Mo{CN(But)(SiMe2But)}(CNBut)5][O3SCF3]

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