Synthesis of diaminoacetylene from cyanido ligands of the octacyanidotungstate complex-Reference-Cited by-同舟云学术

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Synthesis of diaminoacetylene from cyanido ligands of the octacyanidotungstate complex

Published:2024 Issue:29 Volume:48 Page:13196-13205
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Szklarzewicz Janusz¹^ORCID,Hodorowicz Maciej¹^ORCID,Jurowska Anna¹^ORCID

Affiliation:

1. Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, Kraków 30-387, Poland

Abstract

First metal-asisted diaminoacetylene molecule synthesis is achieved. Three salts of [W(CN)6(C2N2H4)]2− ion were isolated and characterized including single crystal structure determination. The formation of diaminoacetylene is described and discussed.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02448F

Reference48 articles.

1. Reductive Coupling of Carbon Monoxide and Alkyl Isocyanide Ligands in Early Transition Metal Complexes: A Review

2. The 15 years of reductive coupling: what have we learned?

3. Carbon Monoxide Coupling Reactions: A New Concept for the Formation of Hexahydroxybenzene

4. Aminocarbyne complexes derived from isocyanides activated towards electrophilic addition

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