Stability of radical-functionalized gold surfaces by self-assembly and on-surface chemistry

Author:

Junghoefer Tobias1234ORCID,Nowik-Boltyk Ewa Malgorzata1234,de Sousa J. Alejandro56789,Giangrisostomi Erika10114,Ovsyannikov Ruslan10114,Chassé Thomas1234,Veciana Jaume5678ORCID,Mas-Torrent Marta5678ORCID,Rovira Concepció5678ORCID,Crivillers Núria5678ORCID,Casu Maria Benedetta1234ORCID

Affiliation:

1. Institute of Physical and Theoretical Chemistry

2. University of Tübingen

3. 72076 Tübingen

4. Germany

5. Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)

6. Networking Research Center on Bioengineering Biomaterials and Nanomedicine (CIBER-BBN)

7. 08193 Bellaterra

8. Spain

9. Laboratorio de Electroquímica

10. Helmholtz-Zentrum Berlin für Materialien und Energie (HZB)

11. 12489 Berlin

Abstract

We have investigated the radical functionalization of gold with a derivative of the perchlorotriphenylmethyl radical using two methods: by chemisorption from the radical solution and by on surface chemical derivation from a precursor.

Funder

Generalitat de Catalunya

Ministerio de Economía y Competitividad

Helmholtz-Zentrum Berlin für Materialien und Energie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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