Interrogating the CISS effect in chiral and paramagnetic organic radicals: the impact of the molecular spin over the total spin polarization-Reference-Cited by-同舟云学术

Interrogating the CISS effect in chiral and paramagnetic organic radicals: the impact of the molecular spin over the total spin polarization

Published:2024 Issue:30 Volume:12 Page:11550-11560
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

De Sousa J. Alejandro¹²^ORCID,Mayorga-Burrezo Paula¹,Míguez-Lago Sandra³^ORCID,Catalán-Toledo José¹^ORCID,Ramos-Tomás Raúl¹,Ortuño Ana³,Zotti Linda A.⁴⁵⁶^ORCID,Palacios Juan José⁵⁶⁷,Campaña Araceli G.³^ORCID,Veciana Jaume¹^ORCID,Crivillers Núria¹^ORCID

Affiliation:

1. Institut de Ciència de Materials de Barcelona (ICMAB, CSIC), Campus de la UAB s/n, Bellaterra, 081093, Spain

2. Laboratorio de Electroquímica, Departamento de Química, Universidad de los Andes, Facultad de Ciencias, Mérida, 5101, Venezuela

3. Departamento de Química Orgánica, Universidad de Granada and Unidad de Excelencia en Química (UEQ), Avda. Fuentenueva s/n, Granada, 18071, Spain

4. Departamento de Física Teórica de la Materia Condensada, Universidad Autónoma de Madrid, Cantoblanco, 28049, Spain

5. Institute of Condensed Matter Physics (IFIMAC), Universidad Autónoma de Madrid, Cantoblanco, 28049, Spain

6. Nicolás Cabrera Institute, Universidad Autónoma de Madrid, Cantoblanco, 28049, Spain

7. Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Cantoblanco, 28049, Spain

Abstract

Enantioenriched PTM radical self-assembled monolayers on gold/nickel are prepared. Their spin filtering ability is not observed experimentally. The lack of CISS observation is explained by DFT quantum transport calculations.

Funder

Agència de Gestió d'Ajuts Universitaris i de Recerca

Ministerio de Ciencia e Innovación

Horizon 2020 Framework Programme

Agencia Estatal de Investigación

European Regional Development Fund

European Commission

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TC/D4TC01389A

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