The mechanism of the Pd-catalyzed formation of coumarins: a theoretical study-Reference-Cited by-同舟云学术

The mechanism of the Pd-catalyzed formation of coumarins: a theoretical study

Published:2015 Issue:2 Volume:17 Page:1347-1353
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nedd S.¹²³⁴,Alexandrova A. N.¹²³⁴⁵

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of California

3. Los Angeles

4. USA

5. California NanoSystems Institute

Abstract

The formation of coumarins via the Pd-catalyzed intramolecular hydroarylation of the C–C triple bond is shown to proceed via the concerted metalation–deprotonation (CMD) mechanism.

Funder

Defense Advanced Research Projects Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP03418J

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