The role of hypervalent iodine(iii) reagents in promoting alkoxylation of unactivated C(sp3)–H bonds catalyzed by palladium(ii) complexes-Reference-Cited by-同舟云学术

The role of hypervalent iodine(iii) reagents in promoting alkoxylation of unactivated C(sp3)–H bonds catalyzed by palladium(ii) complexes

Published:2021 Issue:20 Volume:12 Page:7185-7195
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Abdolalian Payam¹²³⁴^ORCID,Tizhoush Samaneh K.¹²³⁴^ORCID,Farshadfar Kaveh¹²³⁴^ORCID,Ariafard Alireza¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Islamic Azad University

3. Tehran

4. Iran

5. School of Natural Sciences – Chemistry

Abstract

This work uses DFT calculations to explore Pd(ii)-catalysed iodine(iii)-mediated alkoxylation of unactivated C(sp³)–H bonds and reveals how important the isomerization is in triggering the oxidative addition of ArIX₂ to Pd(ii).

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01230D

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