Slow rheological mode in glycerol and glycerol–water mixtures

Author:

Jensen M. H.12345,Gainaru C.678,Alba-Simionesco C.459,Hecksher T.123ORCID,Niss K.123ORCID

Affiliation:

1. Glass & Time, IMFUFA, Department of Science and Environment, Roskilde University

2. DK-4000 Roskilde

3. Denmark

4. Laboratoire Léon Brillouin, CNRS CEA-UMR 12, CEA Saclay

5. 91191 Gif-sur-Yvette Cedex

6. Fakultät Physik, Technische Universität Dortmund

7. 44221 Dortmund

8. Germany

9. France

Abstract

Glycerol–water mixtures were studied at molar concentrations ranging from xgly = 1 (neat glycerol) to xgly = 0.3 using shear mechanical spectroscopy.

Funder

Det Frie Forskningsråd

Danmarks Grundforskningsfond

Commissariat à l'Énergie Atomique et aux Énergies Alternatives

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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3. G. R. Desiraju and T.Steiner , The Weak Hydrogen Bond in Structural Chemistry and Biology , Oxford University Press , Chichester , 1999

4. Y. Maréchal , The hydrogen bond and the water molecule: The physics and chemistry of water, aqueous and bio-media , Elsevier , Amsterdam , 2007

5. THE THIRD LAW OF THERMODYNAMICS. EVIDENCE FROM THE SPECIFIC HEATS OF GLYCEROL THAT THE ENTROPY OF A GLASS EXCEEDS THAT OF A CRYSTAL AT THE ABSOLUTE ZERO

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