Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals-Reference-Cited by-同舟云学术

Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals

Published:2016 Issue:37 Volume:18 Page:26161-26165
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mardyukov Artur¹²³⁴,Schreiner Peter R.¹²³⁴^ORCID

Affiliation:

1. Institute of Organic Chemistry

2. Justus-Liebig University

3. 35392 Giessen

4. Germany

Abstract

The matrix-isolated phenylthiyl radical generated from diphenylsulfide reacts with O₂to give the phenylthiylperoxy radical, which photoisomerizes to the more stable phenylsulfonyl radical.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04278C

Reference58 articles.

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