Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals
Author:
Affiliation:
1. Institute of Organic Chemistry
2. Justus-Liebig University
3. 35392 Giessen
4. Germany
Abstract
The matrix-isolated phenylthiyl radical generated from diphenylsulfide reacts with O2to give the phenylthiylperoxy radical, which photoisomerizes to the more stable phenylsulfonyl radical.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04278C
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