Synthesis, structural peculiarities, and photosensitivity of fluorinated dibenzo-1,2,5,6-tetrathiocines

Author:

Buravlev Alexander A.12,Makarov Alexander Yu.1ORCID,Salnikov Georgy E.1,Genaev Alexander M.1ORCID,Bagryanskaya Irina Yu.1,Nikulshin Pavel V.13,Platonov Vyacheslav E.1,Zibarev Andrey V.1

Affiliation:

1. Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

2. Department of Natural Sciences, National Research University – Novosibirsk State University, 630090 Novosibirsk, Russia

3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russia

Abstract

Synthesized fluorinated dibenzo-1,2,5,6-tetrathiocines are structurally flexible in the solid state (XRD), solution (NMR, NOESY), and gas phase (DFT). In solution under sunlight, they isomerize in rare dibenzo-1,2,3,6-tetrathiocines (XRD).

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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