Ag(<scp>i</scp>)-catalyzed asymmetric (2+4) annulation reaction of 5-alkenyl thiazolones: synthesis of enantioenriched spiro[cyclohexenamines-thiazolones]-Reference-Cited by-同舟云学术

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Ag(i)-catalyzed asymmetric (2+4) annulation reaction of 5-alkenyl thiazolones: synthesis of enantioenriched spiro[cyclohexenamines-thiazolones]

Published:2024 Issue:68 Volume:60 Page:9062-9065
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Choudhary Kavita¹,Deshpande Akanksha Santosh¹,Singh Vinod K.¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, Uttar Pradesh, India

Abstract

We report the first metal-catalyzed (2+4) annulation of 5-alkenyl thiazolones and dicyanoalkylidenes, delivering spiro[cyclohexenamines-thiazolones] with high stereoselectivities.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02957G

Reference45 articles.

1. New development in the enantioselective synthesis of spiro compounds

2. Asymmetric Catalysis for the Synthesis of Spirocyclic Compounds

3. Synthesis of Spiroisoindolinones via Ru(II)-Catalyzed Spiroannulation of N-Acyl Ketimines with Aryl Isocyanates/Isothiocyanates through Aromatic C–H Bond Activation

4. Discovery of a Potent, Orally Active 11β-Hydroxysteroid Dehydrogenase Type 1 Inhibitor for Clinical Study: Identification of (S)-2-((1S,2S,4R)-Bicyclo[2.2.1]heptan-2-ylamino)-5-isopropyl-5-methylthiazol-4(5H)-one (AMG 221)

5. Further Studies with the 2-Amino-1,3-thiazol-4(5H)-one Class of 11β-Hydroxysteroid Dehydrogenase Type 1 Inhibitors: Reducing Pregnane X Receptor Activity and Exploring Activity in a Monkey Pharmacodynamic Model

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