Synthesis and non-conventional structure of square-planar Pd(ii) and Pt(ii) complexes with an N,C,N-chelated stibinidene ligand

Author:

Kořenková Monika12345,Hejda Martin12345ORCID,Štěpnička Petr67895ORCID,Uhlík Filip107895,Jambor Roman12345,Růžička Aleš12345,Dostál Libor12345ORCID

Affiliation:

1. Department of General and Inorganic Chemistry

2. Faculty of Chemical Technology

3. University of Pardubice

4. CZ-532 10, Pardubice

5. Czech Republic

6. Department of Inorganic Chemistry

7. Faculty of Science

8. Charles University in Prague

9. Prague 2

10. Department of Physical and Macromolecular Chemistry

Abstract

Novel Sb(i)→Pd(ii) and Sb(i)→Pt(ii) complexes were shown to form rotamers in solution due to the side-on coordination of the stibinidene ligand.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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