Beyond simple hetero Diels–Alder cycloadditions. A new type of element–ligand cooperativity at N,C,N-coordinated arsinidene and stibinidene centres in the reaction with an electron-deficient alkyne-Reference-Cited by-同舟云学术

Beyond simple hetero Diels–Alder cycloadditions. A new type of element–ligand cooperativity at N,C,N-coordinated arsinidene and stibinidene centres in the reaction with an electron-deficient alkyne

Published:2022 Issue:41 Volume:51 Page:15933-15945
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zechovský Jan¹,Kremláček Vít¹,Erben Milan¹^ORCID,Hejda Martin¹^ORCID,Rychagova Elena²,Jambor Roman¹^ORCID,Růžička Aleš¹^ORCID,Ketkov Sergey²^ORCID,Dostál Libor¹^ORCID

Affiliation:

1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10 Pardubice, Czech Republic

2. G. A. Razuvaev Institute of Organometallic Chemistry RAS, 49 Tropinin St., 603950 Nizhny Novgorod, Russian Federation

Abstract

A remarkable activation of the CC triple bond including its stoichiometric hydrogenation was achieved by N,C,N-coordinated pnictinidenes via an element–ligand cooperative mechanism.

Funder

Russian Science Foundation

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02499C

Reference57 articles.

1. R. H.Crabtree , The Organometallic Chemistry of the Transition Metals , John Wiley & Sons , Hoboken, NJ, USA , 7th edn, 2019

2. Metal-Ligand Cooperation

3. Cooperating Ligands in Catalysis

4. Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

5. Aromaticity in catalysis: metal ligand cooperation via ligand dearomatization and rearomatization

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