The reactivity of antimony and bismuth N,C,N-pincer compounds toward K[BEt3H] – the formation of heterocyclic compounds vs. element–element bonds vs. stable terminal Sb

The reactivity of antimony and bismuth N,C,N-pincer compounds toward K[BEt₃H] – the formation of heterocyclic compounds vs. element–element bonds vs. stable terminal Sb–H bonds

Published:2023 Issue:1 Volume:52 Page:218-227
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Novák Pavel¹,Erben Milan¹^ORCID,Jambor Roman¹^ORCID,Hejda Martin¹^ORCID,Růžička Aleš¹^ORCID,Rychagova Elena²,Ketkov Sergey²^ORCID,Dostál Libor¹^ORCID

Affiliation:

1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10 Pardubice, Czech Republic

2. G.A. Razuvaev Institute of Organometallic Chemistry RAS, 49 Tropinin St., 603950 Nizhny Novgorod, Russian Federation

Abstract

A diverse reactivity of Sb(iii) and Bi(iii) N,C,N pincer complexes toward K[BEt3H] is reported along with a remarkable epimerization of chiral E–E bonded compounds.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03564B

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