Dimerization of a marginally stable disilenyl germylene to tricyclic systems: evidence for reversible NHC-coordination-Reference-Cited by-同舟云学术

Dimerization of a marginally stable disilenyl germylene to tricyclic systems: evidence for reversible NHC-coordination

Published:2016 Issue:13 Volume:52 Page:2799-2802
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Nieder David¹²³⁴,Yildiz Cem B.⁵⁶⁷⁸⁹,Jana Anukul¹²³⁴,Zimmer Michael¹²³⁴,Huch Volker¹²³⁴,Scheschkewitz David¹²³⁴

Affiliation:

1. Krupp-Chair of General and Inorganic Chemistry

2. Saarland University

3. 66125 Saarbrücken

4. Germany

5. Department of Chemistry

6. Faculty of Science and Letters

7. Aksaray University

8. 68100 Aksaray

9. Turkey

Abstract

Reaction of a base-stabilised silagermenylidene with MeLi yields two tricyclic isomeric Si/Ge species via an unsaturated three-membered ring species that is stabilised by excess N-heterocyclic carbene.

Funder

Alfried Krupp von Bohlen und Halbach-Stiftung

Deutsche Forschungsgemeinschaft

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC09878E

Reference34 articles.

1. Stable Heavier Carbene Analogues

2. π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

3. Main-group elements as transition metals

4. Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements

5. Stable singlet carbenes as mimics for transition metal centers

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