A zwitterionic disilanylium from an unsymmetrical disilene-Reference-Cited by-同舟云学术

A zwitterionic disilanylium from an unsymmetrical disilene

Published:2023 Issue:12 Volume:59 Page:1669-1672
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bisai Milan Kumar¹²,Ajithkumar V. S.¹²,Raj K. Vipin²³^ORCID,Vanka Kumar²³^ORCID,Gonnade Rajesh G.²³^ORCID,Sen Sakya S.¹²^ORCID

Affiliation:

1. Inorganic Chemistry and Catalysis Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India

2. Academy of Scientific and Innovative Research (AcSIR), New Ghaziabad 201002, India

3. Physical and Material Chemistry Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India

Abstract

The reaction of PhC(NtBu)2SiSi(SiMe3)3 (1) with Me3SiCH2Cl afforded an unsymmetrical sp2–sp3 disilene, 2, which underwent divergent reactivities with chalcogens.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06954G

Reference26 articles.

1. Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis

2. Functional Disilenes in Synthesis

3. Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements

4. Anionic Reagents with Silicon-Containing Double Bonds

5. Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond

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