Stereodivergent sila-germylenation <i>vs.</i> sila-stannylenation of an internal alkyne-Reference-Cited by-同舟云学术

Stereodivergent sila-germylenation vs. sila-stannylenation of an internal alkyne

Published:2024 Issue:72 Volume:60 Page:9837-9840
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ajithkumar V. S.¹²,Ghanwat Pratiksha B.¹²,Saha Sougata³,Pati Swapan K.³,Sen Sakya S.¹²^ORCID

Affiliation:

1. Inorganic Chemistry and Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

3. Theoretical Sciences Unit, School of Advanced Materials (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore-560064, India

Abstract

We report on the stereodivergent insertion of an electron deficient alkyne, dimethyl acetylene dicarboxylate (DMAD), into the E–Si bond of hypersilyl tetrylenes, PhC(NtBu)2ESi(SiMe3)3 (E = Ge and Sn), at room temperature.

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02101K

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