Group IV heteroadamantanes: synthesis of Si6Sn4and site-selective derivatization of Si6Ge4-Reference-Cited by-同舟云学术

Group IV heteroadamantanes: synthesis of Si₆Sn₄and site-selective derivatization of Si₆Ge₄

Published:2023 Issue:16 Volume:59 Page:2295-2298
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Köstler Benedikt¹^ORCID,Gilmer Jannik¹,Bolte Michael¹^ORCID,Virovets Alexander¹^ORCID,Lerner Hans-Wolfram¹^ORCID,Albert Philipp²,Fantuzzi Felipe³^ORCID,Wagner Matthias¹^ORCID

Affiliation:

1. Institute for Inorganic and Analytical Chemistry, Goethe University Frankfurt, Max-von-Laue-Straße 7, Frankfurt am Main 60438, Germany

2. Smart Materials, Evonik Operations GmbH, Untere Kanalstraße 3, Rheinfelden 79618, Germany

3. School of Chemistry and Forensic Science, University of Kent, Park Wood Rd, Canterbury CT2 7NH, UK

Abstract

Two heteroadamantanes with a Si6Sn4cluster core were prepared in one step synthesis from Me2SnCl2and Si2Cl6/Cl−. The corresponding Si6Ge4heteroadamantane was selectively methylated at all four SiCl3substituents, while both SiCl2groups remained untouched.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06697A

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