Proton transfer vs. oligophosphine formation by P–C/P–H σ-bond metathesis: decoding the competing Brønsted and Lewis type reactivities of imidazolio-phosphines-Reference-Cited by-同舟云学术

Proton transfer vs. oligophosphine formation by P–C/P–H σ-bond metathesis: decoding the competing Brønsted and Lewis type reactivities of imidazolio-phosphines

Published:2020 Issue:47 Volume:49 Page:17401-17413
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cicač-Hudi Mario¹²³⁴,Feil Christoph M.¹²³⁴,Birchall Nicholas¹²³⁴,Nieger Martin⁵⁶⁷⁸^ORCID,Gudat Dietrich¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. University of Stuttgart

3. 70550 Stuttgart

4. Germany

5. Department of Chemistry

6. University of Helsinki

7. 00014 Helsinki

8. Finland

Abstract

Cationic imidazolio-phosphines show two-sided reactivity towards bases, undergoing either Brønsted-type proton transfer to imidazolio-phosphides or autocatalytic Lewis acid/base reaction cascades to yield P-free imidazolium ions and oligophosphines.

Funder

Deutsche Forschungsgemeinschaft

Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03633A

Reference45 articles.

1. Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

2. P4 Activation by Late-Transition Metal Complexes

3. P4 Activation by Main Group Elements and Compounds

4. Functionalization of P4 through Direct P−C Bond Formation

5. Contributions to the chemistry of phosphorus. 218. Monocyclic and polycyclic phosphines

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