A neutral analogue of a phosphamethine cyanine-Reference-Cited by-同舟云学术

A neutral analogue of a phosphamethine cyanine

Published:2022 Issue:17 Volume:51 Page:6533-6536
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cicač-Hudi Mario¹,Kaaz Manuel¹,Birchall Nicholas¹,Nieger Martin²^ORCID,Gudat Dietrich¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany

2. Department of Chemistry, University of Helsinki, P.O. Box 55, 00014 University of Helsinki, Finland

Abstract

Cross coupling of an imidazolio-phosphide with a N-heterocyclic bromo-borane gave a neutral analogue of a phosphamethine cyanine cation embodying a zwitterionic phosphide in which dative bonding of P-centred lone-pairs focuses on the imidazole unit.

Funder

Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00837H

Reference32 articles.

1. The Crystal Structure of a Phosphacyanine

2. A simple route to phosphamethine cyanines from S,N-heterocyclic carbenes

3. The synthesis, characterisation and electronic structure of N-heterocyclic carbene adducts of PI cations

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