New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex-Reference-Cited by-同舟云学术

New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex

Published:2017 Issue:63 Volume:53 Page:8838-8841
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sekino Mio¹²³⁴⁵,Furutachi Hideki¹²³⁴⁵^ORCID,Tojo Rina¹²³⁴⁵,Hishi Ayumi¹²³⁴⁵,Kajikawa Hanako¹²³⁴⁵,Suzuki Takatoshi¹²³⁴⁵,Suzuki Kaito¹²³⁴⁵,Fujinami Shuhei¹²³⁴⁵,Akine Shigehisa¹²³⁴⁵^ORCID,Sakata Yoko¹²³⁴⁵,Ohta Takehiro⁶⁷⁸⁹¹⁰,Hayami Shinya¹¹¹¹²¹³¹⁰^ORCID,Suzuki Masatatsu¹⁴¹⁵¹⁶¹⁷¹⁸

Affiliation:

1. Department of Chemistry

2. Division of Material Sciences

3. Graduate School of Natural Science and Technology

4. Kanazawa University

5. Kakuma-machi

6. Picobiology Institute

7. Graduate School of Life Science

8. University of Hyogo

9. Hyogo 678-1297

10. Japan

11. Graduate School of Science and Technology

12. Kumamoto University

13. Kumamoto 860-8555

14. Depertment of Chemistry and Biochemistry

15. Graduate Engineering

16. Kyushu University

17. 744 Moto-oka

18. Fukuoka 819-0395

Abstract

A diiron(iv)-oxo species (1-oxo) is an essential intermediate in the oxidation reaction initiated by 1-O₂.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC04382A

Reference47 articles.

1. Characterization of the Arene-Oxidizing Intermediate in ToMOH as a Diiron(III) Species

2. Crystallographic and Catalytic Studies of the Peroxide-Shunt Reaction in a Diiron Hydroxylase

3. Mechanistic Studies of Reactions of Peroxodiiron(III) Intermediates in T201 Variants of Toluene/o-Xylene Monooxygenase Hydroxylase

4. In-crystal reaction cycle of a toluene-bound diiron hydroxylase

5. An Fe 2 IV O 2 Diamond Core Structure for the Key Intermediate Q of Methane Monooxygenase

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