Preparations of trans- and cis-μ-1,2-Peroxodiiron(III) Complexes-Reference-Cited by-同舟云学术

Preparations of trans- and cis-μ-1,2-Peroxodiiron(III) Complexes

Published:2023-12-29 Issue:1 Volume:29 Page:205
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Kajita Yuji¹^ORCID,Kubo Masaki²,Arii Hidekazu³,Ishikawa Shinya²,Saito Yamato²,Wasada-Tsutsui Yuko²,Funahashi Yasuhiro⁴^ORCID,Ozawa Tomohiro²,Masuda Hideki¹²^ORCID

Affiliation:

1. Department of Applied Chemistry, Graduate School of Engineering, Aichi Institute of Technology, 1247 Yachigusa, Yakusa-cho, Toyota 470-0392, Japan

2. Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555, Japan

3. Department of Education, Graduate School of Education, University of Miyazaki, Gakuenkibanadai-Nishi, Miyazaki 889-2192, Japan

4. Department of Chemistry, Graduate School of Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-0043, Japan

Abstract

The iron(II) complex with cis,cis-1,3,5-tris(benzylamino)cyclohexane (Bn3CY) (1) has been synthesized and characterized, which reacted with dioxygen to form the peroxo complex 2 in acetone at −60 °C. On the basis of spectroscopic measurements for 2, it was confirmed that the peroxo complex 2 has a trans-μ-1,2 fashion. Additionally, the peroxo complex 2 was reacted with benzoate anion as a bridging agent to give a peroxo complex 3. The results of resonance Raman and 1H-NMR studies supported that the peroxo complex 3 is a cis-μ-1,2-peroxodiiron(III) complex. These spectral features were interpreted by using DFT calculations.

Funder

Japan Society for the Promotion of Science

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/29/1/205/pdf

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