Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment-Reference-Cited by-同舟云学术

Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment

Published:2018 Issue:33 Volume:16 Page:6106-6114
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Takenaka Hiroaki¹²³⁴⁵,Masuhara Yoshihiro¹²³⁴⁵,Narita Kent¹²³⁴⁵,Nokami Toshiki¹²³⁴⁵^ORCID,Itoh Toshiyuki¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Biotechnology

2. Graduate School of Engineering

3. Tottori University

4. Tottori 680-8552

5. Japan

Abstract

The aerobic oxidation took place after the visible light-mediated ring-opening reaction of gem-difluorocyclopropane in the presence of an organic dye and amine to furnish 2,2-difluoro-homoallylic alcohols in good yields.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB01740A

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