Chalcogen bonding mediates the formation of supramolecular helices of azapeptides in crystals
Author:
Affiliation:
1. Department of Chemistry
2. College of Chemistry and Chemical Engineering
3. The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation
4. and iChEM
5. Xiamen University
Abstract
Supramolecular M- and P-helices are formed via intermolecular S⋯S and S⋯O chalcogen bonding of alanine-based azapeptides containing a β-turn structure and equipped with a thiophene group at the N- or C-terminus, respectively.
Funder
National Natural Science Foundation of China
Program for Changjiang Scholars and Innovative Research Team in University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01053K
Reference31 articles.
1. Definition of the chalcogen bond (IUPAC Recommendations 2019)
2. Toward metallocyclopropenium ions: redox cleavage of diorganyldichalcogenides by trichlorocyclopropenium salts
3. Definition of the halogen bond (IUPAC Recommendations 2013)
4. The Origin of Chalcogen-Bonding Interactions
5. Chalcogen Bonding: An Overview
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