Affiliation:
1. Fakultät für Chemie Universität Duisburg-Essen Universitätsstr. 7 45117 Essen Germany
Abstract
AbstractAs a rule, helical structures at the molecular level are formed by non‐planar units. This makes the design of helices, starting from planar building blocks via self‐assembly, even more fascinating. Until now, however, this has only been achieved in rare cases, where hydrogen and halogen bonds were involved. Here, we show that the carbonyl‐tellurium interaction motif is suitable to assemble even small planar units into helical structures in solid phase. We found two different types of helices: both single and double helices, depending on the substitution pattern. In the double helix, the strands are connected by additional Te⋅⋅⋅Te chalcogen bonds. In the case of the single helix, a spontaneous enantiomeric resolution occurs in the crystal. This underlines the potential of the carbonyl‐tellurium chalcogen bond to generate complex three‐dimensional patterns.
Funder
Deutsche Forschungsgemeinschaft
Subject
General Chemistry,Catalysis
Cited by
3 articles.
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