Definition of the chalcogen bond (IUPAC Recommendations 2019)

Author:

Aakeroy Christer B.1,Bryce David L.2,Desiraju Gautam R.3,Frontera Antonio4,Legon Anthony C.5,Nicotra Francesco6,Rissanen Kari7,Scheiner Steve8,Terraneo Giancarlo9,Metrangolo Pierangelo9,Resnati Giuseppe10ORCID

Affiliation:

1. Department of Chemistry , Kansas State University , 1212 Mid-Campus Dr. North , Manhattan, KS 66506-0401 , USA

2. Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and Innovation , University of Ottawa , 10 Marie Curie Private, Ottawa , Ontario K1N 6N5 , Canada

3. Solid State and Structural Chemistry Unit, Indian Institute of Science , Bangalore 560 012 , India

4. Departament de Quımica , Universitat de les Illes Balears , Crta de Valldemossa km 7.5 , 07122 Palma de Mallorca (Baleares) , Spain

5. School of Chemistry, University of Bristol , Bristol BS8 1TS , Avon , UK

6. Department of Biotechnologies and Biosciences , University of Milano Bicocca , Piazza della Scienza 2 , I-20126 Milano , Italy

7. Department of Chemistry, Nanoscience Centre , University of Jyväskylä , POB 34 , Jyväskylä 40014 , Finland

8. Department of Chemistry and Biochemistry , Utah State University , Logan, UT 84322-0300 , USA

9. SBNLab, Department of Chemistry, Materials, and Chemical Engineering “Giulio Natta” , Politecnico di Milano, via Mancinelli 7 , I-20131 Milano , Italy

10. NFMLab, Department of Chemistry, Materials, and Chemical Engineering “Giulio Natta” , Politecnico di Milano, via Mancinelli 7 , I-20131 Milano , Italy

Abstract

Abstract This recommendation proposes a definition for the term “chalcogen bond”; it is recommended the term is used to designate the specific subset of inter- and intramolecular interactions formed by chalcogen atoms wherein the Group 16 element is the electrophilic site.

Funder

International Union of Pure and Applied Chemistry

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

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