Definition of the pnictogen bond (IUPAC Recommendations 2023)

Author:

Resnati Giuseppe1ORCID,Bryce David L.2,Desiraju Gautam R.3,Frontera Antonio4,Krossing Ingo5,Legon Anthony C.6,Metrangolo Pierangelo7,Nicotra Francesco8,Rissanen Kari9,Scheiner Steve10,Terraneo Giancarlo7

Affiliation:

1. NFMLab, Deptartment of Chemistry, Materials, and Chemical Engineering “Giulio Natta” , Politecnico di Milano , Via Mancinelli 7, I-20131 Milano , Italy

2. Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and Innovation , University of Ottawa , 10 Marie Curie Private , Ottawa , Ontario K1N 6N5 , Canada

3. Solid State and Structural Chemistry Unit , Indian Institute of Science , Bangalore , Karnataka 560 012 , India

4. Department of Quımica , Universitat de les Illes Balears , Crta de Valldemossa km 7.5, 07122 Palma de Mallorca (Baleares) , Spain

5. Institute of Inorganic and Analytical Chemistry , Albert-Ludwigs-Universität Freiburg , Albertstrasse 21, D-79104 Freiburg , Germany

6. School of Chemistry , University of Bristol , Bristol BS8 1TS , Avon , UK

7. SBNLab, Department of Chemistry, Materials, and Chemical Engineering “Giulio Natta” , Politecnico di Milano , Via Mancinelli 7, I-20131 Milano , Italy

8. Department of Biotechnologies and Biosciences , University of Milano Bicocca , Piazza della Scienza, 2, I-20126 Milano , Italy

9. Department of Chemistry , University of Jyväskylä , POB 34 , Jyväskylä 40014 , Finland

10. Department of Chemistry and Biochemistry , Utah State University , Logan , UT 84322-0300 , USA

Abstract

Abstract This recommendation proposes a definition for the term “pnictogen bond”; the term pnictogen bond designates a subset of the attractive interactions between an electrophilic region on a pnictogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity.

Funder

International Union of Pure and Applied Chemistry

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

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