Definition of the hydrogen bond (IUPAC Recommendations 2011)

Author:

Arunan Elangannan1,Desiraju Gautam R.2,Klein Roger A.3,Sadlej Joanna4,Scheiner Steve5,Alkorta Ibon6,Clary David C.7,Crabtree Robert H.8,Dannenberg Joseph J.9,Hobza Pavel10,Kjaergaard Henrik G.11,Legon Anthony C.12,Mennucci Benedetta13,Nesbitt David J.14

Affiliation:

1. 1Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India

2. 2Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India

3. 330 Kimberley Road, Chesterton, Cambridge, CB4 1HH, UK

4. 4Department of Chemistry, Laboratory of Intermolecular Interactions, University of Warsaw, Warsaw, PL-02093, Poland

5. 5Department of Chemistry and Biochemistry, 0300 Old Main Hall, Utah State University, Logan, UT 84322, USA

6. 6Medicinal Chemistry Institute, Juan de la Cierva 3, Madrid E-28006, Spain

7. 7Department of Physical and Theoretical Chemistry, Oxford University, South Parks Road, Oxford OX1 3QZ, UK

8. 8Department of Chemistry, 225 Prospect Street, Yale University, New Haven, CT 06511-8499 USA

9. 9Department of Chemistry and Biochemistry, City University of New York, Hunter College, 695 Park Avenue, New York, NY 10065, USA

10. 10Institute of Organic and Biochemistry, Academy of Sciences of Czech Republic, Flemingovo nam 2, Praha CZ 16610, Czech Republic

11. 11Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark

12. 12School of Chemistry, University of Bristol, Bristol BS8 1TS, UK

13. 13Department of Chemistry, University of Pisa, Via Risorgimento 35 Pisa 1-56125, Italy

14. 14Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA

Abstract

A novel definition for the hydrogen bond is recommended here. It takes into account the theoretical and experimental knowledge acquired over the past century. This definition insists on some evidence. Six criteria are listed that could be used as evidence for the presence of a hydrogen bond.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference1 articles.

1. Pure;Arunan;REP Appl Chem,1351

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